Apple removed Web Sharing from Mountain Lion for some unknown reason.
Now you can enable it again easily with these Applescripts.
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Two AppleScript applications, one to start and one to stop Apache and enable Web Sharing in OS X Mountain Lion. When run the first time, one just enters their Administrator password and that's it.
Select the Start Application as a Login item in Preferences > Users and Groups and Web Sharing will be enabled on Start up.

A stand-alone Applescript that provides a way to Start or Stop Apache and Web Sharing in one simple Application.
Enter your Administrator password when the Application first starts up and your set.